Laboratory of Synthesis of organoelement polymers

Laboratory of Synthesis of organoelement polymers

Нeads of laboratory

Since 2018

Kalinina

PhD in Polymer Chemistry
Alexandra Kalinina

tel. +7 (495) 332-58-56
e-mail: kalinina {at} ispm.ru

From 1991 to 2017

Muzafarov

Dr.Sci. in Chemistry
academician Aziz Muzafarov

tel. +7 (495) 332-58-51
e-mail: aziz {at} ispm.ru

Research activity

The Laboratory of the Synthesis of Organoelement Polymers currently working under the supervision of corresponding member of the Russian Academy of Sciences Prof. A.M.Muzafarov, Doctor of Chemistry, was officially founded in 1991, although the actual start to the its history had been given significantly earlier. It was in the late 1970-s when time, location, and desire to do science in the Laboratory of Organosilicon Compounds at the Institute of Organoelement Compounds, a foundation of the Academy of Sciences of the USSR, consolidated young researchers – mainly graduates of the Chair headed by Academician K.A.Andrianov at the Lomonosov Moscow Institute of Fine Chemical Technology. Back then, the Laboratory, the very place where the first Ph.D. defenses took place, was supervised by Academician K.A.Andrianov (and later Prof. A.A.Zhdanov). This scientific school brought extremely rich harvest, and in 1989 these scientists, experienced, but still occupying junior research positions, began their independent life as the Group of the Synthesis of Highly Functional Volume-Growing Systems at the Institute of Synthetic Polymeric Materials then headed by Academician N.S.Enikolopov. In 1991 this group underwent transformation into the currently existing Laboratory. Since that moment, it has significantly grown up by the number of workers, who inherited not only the enthusiasm to continue as a consolidated community, but also the abilities to succeed despite uneasy conditions. Somewhat later the group was joined by graduates of the Chemistry and Physics Departments at Lomonosov Moscow State University and a number of young researchers – alumni of the Graduate School at the Institute of Synthetic Polymeric Materials, a foundation of the Russian Academy of Sciences.

Main scientific directions

The Laboratory is engaged in research in the following directions:

  • development of methods of the synthesis and investigation of the properties of organosilicon polymers with different structures and having different applications;
  • synthesis and investigation of organosilicon dendrimers, hyperbranched polymers and other molecular nano-objects
  • synthesis of inorganic polymeric systems and pre-ceramic materials;
  • synthesis and investigation of the properties of functional materials for organic electronics and photonics.

Staff                                      

Chief scientific officer:
Aziz Muzafarov

Senior research scientists:
Olga Gorbatsevich
Nina Demchenko
Galina Ignatyeva
Valentina Kazakova
Alexandra Kalinina
Ivan Meshkov
Denis Shragin
Elena Tatarinova
Nadezhda Tebeneva
Nataliya Vasilenko

Research fellows:
Alexandra Bystrova
Fedor Drozdov
Sergey Milenin
Dmitriy Migulin
Marina Obrezkova
Alexandr Tarasenkov

Junior researchers:
Kirill Borisov
Vadim Gorodov
Evgeniya Talalaeva
Pavel Tikhonov

Graduate students:
Ulyana Andropova
Gleb Polyakov
Elizaveta Selezneva
Pavel Tikhonov
Yuliya Vysochinskaya
Sofya Zimovec

Students:
Svetlana Avisova RTU MIREA
Yulia Alferova RTU MIREA
Pavel Belyakov
Galina Golovacheva RTU MIREA
Ksenia Klokova RTU MIREA
Yulia Korotkova RTU MIREA
Nikita Yakhontov RTU MIREA

Main publications overview

2018

Use of MnCl 2/t BuOOH oxidizing system for conversion of p-tolyldisiloxanes to p-carboxyphenyldisiloxanes

Goncharova I. K., Arzumanyan A. V., Milenin S. A., Muzafarov A. M.

Journal of Organometallic Chemistry, 2018, 28–30; DOI: 10.1016/j.polymer.2018.01.047

Core/shell hybrid dendrimers: Controllable rigidity determines molecular behaviour

Serkova E. S., Krasnova I. Y., Milenin S. A., Selezneva E. V., Tatarinova E. A., Boldyrev K. L., Korlyukov A. A.,  Zubavichus Y. V.,  Buzin M. I., Serenko O. A., Shifrina Z. B.

Polymer, 2018, 83-91; DOI: 10.1016/j.polymer.2018.01.047

Simple and fast method for producing flexible superhydrophobic aerogels by direct formation of thiol-ene networks in scCO 2

Temnikov M. N., Kononevich Y. N., Meshkov I. B., Buzin M. I., Vasil'ev V. G., Nikiforova G. G., Muzafarov A. M.

Polymer, 2018, 255-266; DOI: 10.1016/j.polymer.2018.01.067

Copper-Catalyzed Oxidation of Hydrosilanes: A New Method for the Synthesis of Alkyl- and Siloxysilanols

Arzumanyan A. V., Goncharova I. K., Novikov R. A., Milenin S. A., Muzafarov A. M.

Synlett, 2018, 489-492; DOI: 10.1055/s-0036-1591512

A study of the hydrosilylation approach to a one-pot synthesis of silicone aerogels in supercritical CO2

Elmanovich I. V., Pryakhina T. A., Vasil’ev V. G., Gallyamov M. O., Muzafarov A. M.

The Journal of Supercritical Fluids, 2018, 512-518; DOI: 10.1016/j.supflu.2017.11.017

The use of noncovalently modified carbon nanotubes for preparation of hybrid polymeric composite materials with electrically conductive and lightning resistant properties

Kondrashov S. V., Soldatov M. A., Gunyaeva A. G., Shashkeev K. A., Komarova O. A., Barinov D. Y., Yurkov G. Y., Shevchenko V. G., Muzafarov A. M

Journal of Applied Polymer Science, 2018, 46108; DOI: 10.1002/app.46108

Sodiumoxy (aminopropyl) alkoxysilanes-AB2 type monomers for the synthesis of hyperbranched poly (aminopropyl) alkoxysiloxanes and their derivatives

Migulin D., Milenin S., Cherkaev G., Svidchenko E., Surin N., & Muzafarov A

Journal of Organometallic Chemistry, 2018, 24-32; DOI: 10.1016/j.jorganchem.2017.11.028

Probing the 1H spin distribution in hybrid organic-inorganic gels by multiple-quantum NMR spectroscopy

Vasil'ev S.G., Volkov V.I., Tatarinova E.A., Muzafarov A.M., Sipyagina N.A., Lermontov S.A. 

Journal of Non-Crystalline Solids, 2018, 6–15; DOI: 10.1016/j.jnoncrysol.2018.03.014

Mechanochemistry – a new powerful green approach to direct synthesis of alkoxysilanes

Temnikov M.N.,  Anisimov A.A., Zhemchugov P.V., Kholodkov D.N., Goloveshkin A.S.,  Naumkin A.V., Chistovalov S.M., Katsulis D.E., Muzafarov A.M.

Green Chemistry, 2018; DOI: 10.1039/C7GC03862C

Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

Arzumanyan A. V., Goncharova I. K., Noviko R. A., Milenin S., Boldyrev K. L., Solyev P. N., Volodin A. D., Smol’yakov A. F., Korlyukov A., Muzafarov A.

Green Chem, 2018, 1467-1471; DOI: 10.1039/C8GC00424B

2017

Thermodynamic properties of first- and third-generation carbosilane dendrimers with terminal phenyldioxolane groups

Smirnova N. N., Sologubov S. S., Sarmini Yu. A., Markin A. V., Novozhilova N. A., Tatarinova E. A., Muzafarov A. M.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 2317-2325; DOI: 10.1134/S0036024417110279

Hybrid materials based on polymethylsilsesquioxanes containing Fe, Pt, and Fe-Pt metallic nanoparticles

Vasil'kov A. Yu., Migulin D. A., Naumkin A. V., Zubavichus Ya. V., Budnikov A. V., Ellert O. G., Maksimov Yu. V., Muzafarov A. M.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 2188-2194; DOI: 10.1134/S0036024417110310

Formation of Honeycomb Films Based on Cardo Polyimide Modified with Fluorocontaining Organosilicon Copolymers by Breath Figures Method

Parshina M.S., Soldatov M.A., Sapozhnikov D.A., Serenko O.A., Muzafarov A.M.

MACROMOLECULAR SYMPOSIA, 2017, 1700035; DOI: 10.1002/masy.201700035

BODIPY-based dye for no-wash live-cell staining and imaging

Pakhomov A.A., Deyev I.E., Ratnikova N.M., Chumakov S.P., Mironiuk V.B., Kononevich, Yu.N., Muzafarov A.M., Martynov V.I.

BIOTECHNIQUES, 2017, 77-79; DOI: 10.2144/000114577

Synthesis and structures of novel tetra- and pentanuclear copper sandwich-like metallasiloxanes with pyridine ligands

Kononevich Yu.N., Anisimov A.A., Korlyukov A.A., Tsareva U.S., Shchegolikhina O.I., Muzafarov A.M.

MENDELEEV COMMUNICATIONS, 2017, 332-334; DOI: 10.1016/j.mencom.2017.07.002

Synthesis and crystal structure of a meso-decene-BODIPY dye as a functional bright fluorophore for silicone matrices

Pakhomov A.A., Mironiuk V.B., Kononevich Yu.N., Korlyukov A.A., Volodin A.D., Pryakhina T.A., Martynov V.I., Muzafarov A.M.

MENDELEEV COMMUNICATIONS, 2017, 363-365; DOI: 10.1016/j.mencom.2017.07.014

Multiferroic based on nanoparticles consisting of a silica nucleus and a shell of spin-variable iron complexes

Aleksandrov A. I., Tebeneva N. A., Shevchenko V. G., Aleksandrov I. A., Meshkov I. B., Muzafarov A. M.

JETP LETTERS, 2017, 51-56; DOI: 10.1134/S0021364017130057

New star-like polydimethylsiloxanes: synthesis, properties, and application

Vysochinskaya Yu. S., Gorodov V. V., Anisimov A. A., Boldyrev K. L., Buzin M. I., Naumkin A. V., Maslakov K. I., Peregudov A. S., Shchegolikhina O. I., Muzafarov A. M.

RUSSIAN CHEMICAL BULLETIN, 2017, 1094-1098; DOI: 10.1007/s11172-017-1859-8

Formation of a physical crosslinked structure in polydimethylsiloxanes modified with long-chain hydrocarbon substituents with polar fragments

Vasil'ev V. G., Pryakhina T. A., Shragin D. I., Kononevich Yu. N., Papkov V. S., Muzafarov A. M.

POLYMER SCIENCE SERIES B, 2017, 320-327; DOI: 10.1134/S1560090417030150

Synthesis and photophysical properties of halogenated derivatives of (dibenzoylmethanato)boron difluoride

Kononevich Yu.N., Surin N.M., Sazhnikov V.A., Svidchenko E.A., Aristarkhov V.M., Safonov A.A., Bagaturyants A.A., Alfimov M.V., Muzafarov A.M.

PECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2017, 177-184; DOI: 10.1016/j.saa.2016.12.025

Synthesis and properties of water-soluble silica nanoparticles

Gorbatsevich O. B., Kholodkov D. N., Kurkin T. S., Malakhova Yu. N., Strel'tsov D. R., Buzin A. I., Kazakova V. V., Muzafarov A. M.

RUSSIAN CHEMICAL BULLETIN, 2017, 409-417; DOI: 10.1007/s11172-017-1748-1

The effect of hafnium alkoxysiloxane precursor structure of disperse phase on the morphology of nanocomposites based on polyaryleneetherketone

Andropova U.S., Parshina M.S., Askadskii A.A., Serenko O.A., Muzafarov A.M., Tebeneva N.A., Tarasenkov A.N.

Polymer Science. Series B, 2017, 202-209; DOI: 10.7868/S2308113917020127

Non-catalytic hydrolytic polycondensation of dialkoxydiorganosilanes under elevated pressure

Kalinina A.A., Muzafarov A.M., Zhiltsov A.S., Pigaleva M.A., Elmanovich I.V., Molodtsova Y.A., Kotov V.M., Gallyamov M.O.

Russian Chemical Bulletin, 2017, 355-361; DOI: 10.1007/s11172-017-1740-9

Adsorption properties of pyridylphenylene dendrimers

Serenko O., Strashnov P., Kapustin G., Kalinin M., Kuchkina N., Serkova E., Shifrina Z., Muzafarov A.

RSC ADVANCES, 2017, 7870-7875; DOI: 10.1039/c6ra27064f

Synthesis, Characterisation, and Investigation of Thermosensitive Star-Shaped Poly(2-Isopropyl-2-Oxazolines) Based on Carbosilane Dendrimers

Amirova A., Rodchenko S., Makhmudova Zh., Cherkaev G., Milenin S., Tatarinova E., Kurlykin M., Tenkovtsev A., Filippov A.

Macromolecular chemistry and physics, 2017, 1600387; DOI: 10.1002/macp.201600387

Synthesis and thermal and rheological properties of carboxyl-containing polydimethylsiloxanes

Gorodov V.V., Demchenko N.V., Shragin D.I., Muzafarov A.M., Buzin M.I., Vasil'ev V.G., Papkov V.S.

Russian Chemical Bulletin, 2017, 1290-1299; DOI: 10.1007/s11172-017-1887-4

Synthesis and Properties of MQ Copolymers: Current State of Knowledge

Tatarinova E., Vasilenko N., Muzafarov A.  

Molecules, 2017, 1768; DOI: 10.3390/molecules22101768

The Suzuki modification of functional polydimethylsiloxanes

Drozdov F.V., Cherkaev G.V., Muzafarov A.M.

Mendeleev Commun, 2017, 571-572; DOI: 10.1016/j.mencom.2017.11.010

Investigation of Melts of Polybutylcarbosilane Dendrimers by 1H NMR Spectroscopy

Matveev V. V.,  Markelov D. A., Dvinskikh S. V., Shishkin A. N., Tyutyukin K. V., Penkova A. V., Tatarinova E. A., Ignat'eva G. M., Milenin S. A.

Scientific Reports, 2017, 13710; DOI: 10.1038/s41598-017-13743-z

Influence of a hydrophobic core on thermoresponsive behavior of dendrimer-based star-shaped poly (2-isopropyl-2-oxazoline) in aqueous solutions

Amirova A., Rodchenko S., Milenin, S., Tatarinova E., Kurlykin M., Tenkovtsev A., & Filippov A.

Journal of Polymer Research, 2017, 124; DOI: 10.1007/s10965-017-1285-5

Synthesis of thioether-containing carbosilane dendrimers with sterically shielded sulfur atoms

 Tarasenkov А. N.,  Getmanova E. V.,  Tatarinova E. A.,  Buzin М. I.,  Demchenko N. V.,  Cherkaev G. V.,  Muzafarov А. М.

Russ. Chem. Bull, 2017, 1675—1685; DOI: 10.1007/s11172-017-1940-3

Complexes of CuCl2 with G1-8S-Dec dendrimer. DFT calculations of the structure and physicochemical properties

Alexandrov A. I., Tarasenkov A. N., Alexandrov I. A., Metlenkova I. Y., Kiselev S. S., & Borisov, Y. A. 

Russian Chemical Bulletin, 2017, 813-820; DOI: 10.1007/s11172-017-1812-x

Superhydrophobic conducting coatings based on silicone matrix and carbon nanotubes

Shashkeev, K. A., Nagornaya V. S., Volkov I. A., Kondrashov S. V., D’yachkova T. P., Kondakov A. I., Borisov K. M., Yurkov G. Yu.

Russian Journal of Applied Chemistry, 2017, 1107-1116; DOI: 10.1134/S1070427217070138

Dicationic polysiloxane ionic liquids

Krasovskiy, V. G., Glukhov, L. M., Chernikova, E. A., Kapustin, G. I., Gorbatsevich, O. B., Koroteev, A. A., & Kustov, L. M. 

Russian Chemical Bulletin, 2017, 1269-1277; DOI: 10.1007/s11172-017-1884-7

2016

Hydrolytic polycondensation of methylalkoxysilanes under pressure

Kalinina A.A., Kholodkov D.N., Meshkov I.B., Muzafarov A.M., Pigaleva M.A., Elmanovich I.V., Molodtsova Y.A., Gallyamov M.O.

Russian Chemical Bulletin, 2016, 1104-1109; DOI: 10.1007/s11172-016-1419-7

Synthesis of dimethylcyclosiloxanes in the active medium

Kalinina A.A., Talalaeva E.V., Vasilenko N.G., Demchenko N.V., Muzafarov A.M., Molodtsova Y.A., Demchenko A.I.

Russian Chemical Bulletin, 2016, 1013-1019; DOI: 10.1007/s11172-016-1405-0

Molecular silicasol-based barrier coatings for organic electronics

Sizov A.S., Meshkov I.B., Yablokov M.Y., Agina E.V., Muzafarov A.M., Ponomarenko S.A., Bessonov A.A.

Nanotechnologies in Russia, 2016, 617-624; DOI: 10.1134/S1995078016050189

Preparation of Chemosensor Materials Based on Silica Nanoparticles with Covalently Anchored Fluorophores by Inkjet Printing

Ionov D. S., Yurasik G. A., Molchanov S. P., Sazhnikov V. A., Aristarkhov V. M., Kononevich Yu. N., Meshkov I. B., Voronina N. V., Muzafarov A. M., Alfimov M. V.

Nanotechnologies in Russia, 2016, 444–453; DOI: 10.1134/S199507801604008X

Phase State and Rheology of Organosilicon Nanocomposites with Functionalized Hyperbranched Nanoparticles

Ilyin S.O., Polyakova M.Yu., Makarova V.V., Meshkov I.B., Kulichikhin V.G.

Polymer Science, Series A., 2016, 985–993; DOI: 10.1134/S0965545X16060080

Synthesis of the first hyperbranched polyorganoethoxysilsesquioxanes and their chemical transformations to functional core-shell nanogel systems

Migulin D., Tatarinova E., Meshkov I., Cherkaev G., Vasilenko N., Buzin M., Muzafarov A.

Polym Int, 2016, 72–83; DOI: 10.1002/pi.5029

Rheological properties of sulfur-containing hyperbranched polycarbosilanes and related magnetic compositions

Tarasenkov A.N., Getmanova E.V., Muzafarov A.M., Vasil´ev V.G., Buzin M.I., Kramarenko E.Y., Pak G.G.

Russian Chemical Bulletin, 2016, 1086-1096; DOI: 10.1007/s11172-016-1417-9

Complexes of CuCl2 with low generation dendrimer G1-4S-Bu. Density functional calculations of structure and physicochemical properties

Alexandrov A.I., Metlenkova I.Y., Tarasenkov A.N., Borisov Y.A.

Russian Chemical Bulletin, 2016, 407-413; DOI: 10.1007/s11172-016-1313-3

Structure and properties of organic-inorganic nanocomposites based on polyaryleneetherketone

Tebeneva N.A., Tarasenkov A.N., Buzin M.I., Shaposhnikova V.V., Serenko O.A., Muzafarov A.M.

Russian Chemical Bulletin, 2016, 1097-1103; DOI: 10.1007/s11172-016-1418-8

Sodium cis-tetratolylcyclotetrasiloxanolate and cis-tritolylcyclotrisiloxanolate: Synthesis, structure and their mutual transformations

Anisimov A.A., Zhemchugov P.V., Milenin S.A., Goloveshkin A.S., Tsareva U.S., Bushmarinov I.S., Korlyukov A.A., Takazova R.U., Molodtsova Yu.A., Muzafarov A.M., Shchegolikhina O.I.

Journal of Organometallic Chemistry, 2016, 103-111; DOI: 10.1016/j.jorganchem.2016.09.023

Synthesis and structure of new polyhedral Ni, Na-and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

Anisimov A. A., Kononevich Y. N., Zhemchugov P. V., Milenin S. A., Korlyukov A.A., Tsareva U S., Peregudov A. S., Dorovatovskii P. V., Molodtsova Y.A., Takazova R. U., Shchegolikhina O. I., Muzafarov A. M. 

RSC Advances, 2016, 22052-22060; DOI: 10.1039/C5RA26414F.

Cu (II)-Silsesquioxanes as Secondary Building Units for Construction of Coordination Polymers: A Case Study of Cesium-Containing Compounds

Korlyukov A. A., Vologzhanina A. V., Buzin M. I., Sergienko N. V., Zavin B. G., Muzafarov A. M. 

Crystal Growth & Design, 2016, 1968-1977; DOI: 10.1021/acs.cgd.5b01554

Acyclic polyphenylsilsesquioxane: synthesis and properties

Temnikov M. N., Buzin M. I., Demchenko N. V., Cherkaev G. V., Vasilenko N. G., Muzafarov A. M.

Mendeleev Communications, 2016, 121-123; DOI: 10.1016/j.mencom.2016.03.012

Magnetorheological fluids based on a hyperbranched polycarbosilane matrix and iron microparticles

Vasiliev V. G., Sheremetyeva N. A., Buzin M. I., Turenko D. V., Papkov V. S., Klepikov I. A., Razumovskaya I. V.,. Muzafarov A. M, Kramarenko E. Yu.

Smart Materials and Structures, 2016, 55016; DOI: 10.1088/0964-1726/25/5/055016

Polymer composites with surface modified SiO2 nanoparticles: Structures, properties, and promising applications

Serenko O.A., Muzafarov A.M.

Polymer Science Series B, 2016, 93-101; DOI: 10.1134/S1811238216010112

Hybrid materials based on core-shell polyorganosilsesquioxanes modified with iron nanoparticles

Vasil’kov A.Yu., Migulin D. A., Naumkin A. V., Belyakova O. A., Zubavichus Y. V., Abramchuk S. S., Maksimov Y. V., Novichikhind S. V. and Muzafarova A. M. 

Mendeleev Communications, 2016, 187-190; DOI: 10.1016/j.mencom.2016.04.002

Organosilicon compounds in supercritical carbon dioxide: Synthesis, polymerization, modification, and production of new materials

Pigaleva M.A., Elmanovich I.V., Gallyamov M.O., Temnikov M.N., Muzafarov A.M.

Polymer Science. Series B, 2016, 235-270; DOI: 10.1134/S1560090416030118

Surface modification of epoxy resin by amphiphilic fluoroorganosiloxane copolymers

Soldatov M.A., Naumkin A.V., Serenko O.A., Pertsin A.I., Pereyaslavtsev A.Y.

Russian Chemical Bulletin, 2016, 1116-1118; DOI: 10.1007/s11172-016-1421-0

Solution properties of comb‐like polymers consisting of dimethylsiloxane monomer units

Filippov A., Kozlov A., Tarabukina E., Obrezkova M., Muzafarov A. 

Polymer International, 2016, 393–399; DOI: 10.1002/pi.5067

Organosilicon fluoro-containing polymer brushes based on epoxy matrix: XPS analysis

Naumkin A.V., Volkov I.O., Pertsin A.I., Soldatov M.A., Streltsov D.R., Pereyaslavtsev A.Y.

Russian Chemical Bulletin, 2016, 1072-1075; DOI: 10.1007/s11172-016-1415-y

(Monosodiumoxy)organoalkoxysilanes (Rebrov Salts)—Polyfunctional Monomers for Silicone Syntheses

Muzafarov A.M.

Efficient Methods for Preparing Silicon Compounds, 2016, 179-181; DOI: 10.1016/B978-0-12-803530-6.00013-5

Small-angle x-ray scattering study of polymer structure: Carbosilane dendrimers in hexane solution

Shtykova E. V., Feigin L. A., Volkov V. V., Malakhova Y. N., Streltsov D. R., Buzin A. I., Chvalun S.N., Katarzhanova E. Yu., & Muzafarov A. M.

Crystallography Reports, 2016, 815-825; DOI: 10.1134/S1063774516050199

Synthesis, crystal structure and optical properties of a new meso-acrylate BODIPY dye

Pakhomov A. A., Kononevich Y. N., Korlyukov A. A., Martynov V. I., Muzafarov A. M. 

Mendeleev Communications, 2016, 196-198; DOI: 10.1016/j.mencom.2016.04.005

Synthesis and photophysical properties of a new BODIPY-based siloxane dye

Pakhomov A. A., Kononevich Y. N., Stukalova M. V., Svidchenko E. A., Surin N. M., Cherkaev G. V., Shchegolikhina V. I., Martynov O. I., Muzafarov A. M.

Tetrahedron Letters, 2016, 979-982; DOI: 10.1016/j.tetlet.2016.01.059

Direct-write printing of reactive oligomeric alkoxysilanes as an affordable and highly efficient route for promoting local adhesion of silver inks on polymer substrates

Kirikova M. N., Agina E. V., Bessonov A. A., Sizov A. S., Borshchev O. V., Trul A. A., Muzafarov A.M., Ponomarenko S. A.

Journal of Materials Chemistry, 2016, 2211-2218; DOI: 10.1039/C5TC03497C

Polymers Beyond Chlorine. In Chemistry Beyond Chlorine

Muzafarov A.M.

Springer International Publishing, 2016, 317-330; DOI: 10.1007/978-3-319-30073-3_11

Solution Properties of New “core-shell” Structured Polyorganosilsesquioxanes with Two Different Types of “core-shell

Amirova A. I., Golub O. V., Migulin D. A., Muzafarov A.M.

International Journal of Polymer Analysis and Characterization, 2016, 214-220; DOI: 10.1080/1023666X.2016.1136867

Calorimetric study of carbosilane dendrimers of the third and sixth generations with phenylethyl terminal groups

Sologubov S. S., Markin A. V., Smirnova N. N., Rybakova Y. A., Novozhilova N. A., Tatarinova E. A., & Muzafarov A. M.

Journal of Thermal Analysis and Calorimetry, 2016, 595–606; DOI: 10.1007/s10973-016-5301-5

Development of a method for introducing 1-aminophosphonate fragment in a siloxane matrix

Khairova R. R., Milenin S. A., Cherkaev G. V., Stoikov I. I., Muzafarov A. M.

Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 1617-1618; DOI: 10.1080/10426507.2016.1217218

Effect of Hybrid Nanoparticles on Glass Transition Temperature of Polymer Nanocomposites

Roldughin V. I., Serenko O. A., Getmanova E.V., Novozhilova N. A., Nikifirova G. G., Buzin M. I., Chvalun S. N., Ozerin A. N., Muzafarov A. M.

Polymer Composites, 2016, 1978–1990; DOI: 10.1002/pc.23376

Synthesis, Characterization, and Investigation of Thermosensitive Star‐Shaped Poly (2‐isopropyl‐2‐oxazolines) Based on Carbosilane Dendrimers

Amirova A., Rodchenko S., Makhmudova Z., Cherkaev G., Milenin S., Tatarinova E., Kurlykin M., Tenkovtsev A., Filippov A.

Macromolecular Chemistry and Physics, 2016, 1600387; DOI: 10.1002/macp.201600387

Interaction of organodialkoxysilanolates with carbon dioxide

Temnikov M. N., Cherkun N. V., Boldyrev K. L., Zimovets S. N., Kononova E. G., Elmanovich M.O. Gallyamov I. V., Muzafarov А.M.

RSC Advances, 2016, 105161-105165; DOI: 10.1039/C6RA19758B

2015

Solution Behavior of Hyperbranched Polymethylsilsesquioxane with Intramolecular Cycles

Amirova A. I., Golub O. V., Meshkov I. B., Migulin D. A., Muzafarov A. M., Filippov A. P.

International Journal of Polymer Analysis and Characterization, 2015, 268-276; DOI: 10.1080/1023666X.2015.1013185

Polycondensation of Diethoxydimethylsilane in Active Medium

Kalinina A., Strizhiver N., Vasilenko N., Perov N., Demchenko N., Muzafarov A.

Silicon, 2015, 95-106; DOI: 10.1007/s12633-014-9233-z

Comb-Like Polymethylsiloxanes. Synthesis, Structure and Properties

Obrezkova M.A., Kalinina A.A., Pavlichenko I.V., Vasilenko N.G.,· Mironova M.V., Semakov A.V., Kulichikhin V.G., Buzin M.I., Muzafarov A.M.

Silicon, 2015, 177-189; DOI: 10.1007/s12633-014-9257-4

Novel Cross-Linked Luminescent Silicone Composites Based on Reactive Nanostructured Organosilicon Luminophores

Skorotetcky M. S., Borshchev 0. V., Surin N. M., Meshkov I. B., Muzafarov A. M., Ponomarenko S. A.

Silicon, 2015, 191-200; DOI: 10.1007/s12633-014-9256-5

Synthesis of Fluorine-containing-Organosilicon Oligomer in Trifluoroacetic Acid as Active Medium

Soldatov M.A., Sheremetyeva N.A., Serenko O.A., Muzafarov A.M.

Silicon, 2015, 211-216; DOI: 10.1007/s12633-014-9232-0

Polylactide and hybrid silicasol nanoparticle-based composites

Zhiltsov A., Gritsenko O.,  Kazakova V., Gorbatsevitch O., Bessonova N., Askadskii A.,  Serenko O., Muzafarov A. 

JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 41894; DOI: 10.1002/app.41894

Hydrolytic polycondensation of diethoxydimethylsilane in carbonic acid

Kalinina A.A., Elmanovich I.V., Temnikov M.N., Pigaleva M.A., Zhiltsov A.S., Gallyamov M.O., Muzafarov A.M.

RSC ADVANCES, 2015, 5664-5666; DOI: 10.1039/C4RA13619E.

Novel Approach to Synthesis of Monodisperse Polymeric Microspheres: Heterophase Polymerization of Styrene and Methyl Methacrylate in Presence of Water-Insoluble Functional PDMSs

Shragin D. I., Gritskova I. A., Kopylov V. V., Milushkova E. V., Zlydneva L. A., Levachev S. M.

Silicon, 2015, 217-227; DOI: 10.1007/s12633-014-9265-4

Comparison of Effectiveness of Various Approaches to Direct Synthesis of Alkoxysilanes

Temnikov M. N., Zhiltsov A. S., Kotov V. M., Krylova I. V., Egorov M. P., Muzafarov A. M. 

Silicon, 2015, 69-78; DOI: 10.1007/s12633-014-9236-9

Synthesis of Carbosilane Dendrimers with 2-Phenylethyl End Groups and Influence of Generation Number on Glass Transition Temperature of PS-based Composites

Novozhilova N. A., Serenko O. A., Roldughin V. I., Askadskii A. A., Muzafarov A. M. 

Silicon, 2015, 155-164; DOI: 10.1007/s12633-014-9223-1

Synthesis and Characterization of Organo-Inorganic Nanoobjects Based on Hyperbranched Polyethoxysiloxanes

Zhiltsov A. S., Boldyrev K. L., Gorbatsevitch O. B., Kazakova V. V., Demchenko N. V., Cherkaev G. V., Muzafarov A. M.

Silicon, 2015, 165-176; DOI: 10.1007/s12633-014-9229-8

Calorimetric and infrared studies of carbosilane dendrimers of the third generation with ethyleneoxide terminal groups

Markin A.V., Sologubov S.S., Smirnova N.N., Knyazev A.V., Maczka, M., Ptak, M., Novozhilova N.A.,  Tatarinova, E.A.,  Muzafarov A.M.

Thermochimica Acta, 2015, 144-151; DOI: 10.1016/j.tca.2015.08.028

Preparation and application of a BODIPY-labeled probe for a real-time polymerase chain reaction

Ilnitskaya E.V.,  Kononevich Y.N., Muzafarov A.M., Rzhevskiy S.A., Shadrin I.A., Babaev E.V., Martynov V.I.,  Pakhomov A.A.

RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY, 2015, 451-453; DOI: 10.1134/S1068162015040068

Effect of the rigid core of the filler on the properties of melt-mixed polystyrene/core-shell particle nanocomposites

Serenko O.A., Mironova M.V., Novozhilova N.A., Strashnov P.V., Getmanova E.V., Askadskii A.A., Shevchenko V.G., Kulichikhin V.G., Muzafarov A.M.

MATERIALS CHEMISTRY AND PHYSICS, 2015, 16-28; DOI: 10.1016/j.matchemphys.2015.02.013

Influence of branching regularity on the behavior of hyperbranched polymers in solution

Filippov A, Amirova A.I., Kirila T., Belyaeva E.V., Sheremetyeva N.A., Muzafarov A.M.

POLYMER INTERNATIONAL, 2015, 780-786; DOI: 10.1002/pi.4852

Synthesis of alkoxybenzylmethylsilanes and polybenzylmethylsiloxane polymers on their basis

Milenin S.A., Kalinina A.A., Gorodov V.V., Vasilenko N.G., Muzafarov A.M., Buzin M.I.

Russian Chemical Bulletin, 2015, 2498-2504; DOI: 10.1007/s11172-015-1183-0

Nanocomposites Based on Polyethylene and Modified Silica Phase

Nikonorova N. I., Trofimchuk E. S., Meshkov I. B., Volynskii A. L., Bakeev N. F., Muzafarov A. M.

Nanotechnologies in Russia, 2015, 75-80; DOI: 10.1134/S1995078015060087

Synthesis, rheological, and thermal properties of polydimethylsiloxanes modified with long-chain hydrocarbon substituents with polar fragments

Pryakhina T.A., Shragin D.I., Kononevich Y.N., Vasiĺev V.G., Buzin M.I., Papkov V.S., Muzafarov A.M. 

Russian Chemical Bulletin, 2015, 605-612; DOI: 10.1007/s11172-015-0906-6

Organosilicon surfactants: Effects of structure on the kinetics of heterophase polymerization of methyl methacrylate and behavior in Langmuir films on the surface of water

Gritskova I.A., Milushkova E.V., Ezhova A.A., Lukashevich A.D., Prokopov N.I., Malakhova Y.N., Kopylov V.M., Shragin D.I., Buzin A.I., Levachev S.M.

Polymer Science. Series B, 2015, 560-566; DOI: 10.1134/S1560090415060068

Thermodynamic Properties of Carbosilane Dendrimers of the Sixth Generation with Ethyleneoxide Terminal Groups

Sologubov S., Markin A. V., Smirnova N. N., Novozhilova N. A., Tatarinova E. A., & Muzafarov A. M.

J. Phys. Chem. B, 2015, 14527–14535; DOI: 10.1021/acs.jpcb.5b06786

Effect of hybrid nanoparticles on glass transition temperature of polymer nanocomposites

Roldughin V. I., Serenko O. A., Getmanova E. V., Novozhilova N. A., Nikifirova G. G., Buzin M. I., Chvalun S.N., Ozerin A. N., Muzafarov A. M.

Polymer Composites, 2015, 1978 – 1990; DOI: 10.1002/pc.23376

Biphase H2O/CO2 system as versatile reaction medium for organic synthesis

Pigaleva M. A., Elmanovich I., Kononevich Yu. N., Gallyamov M., Muzafarov A.

RSC Adv, 2015, 103573 – 103608; DOI: 10.1039/C5RA18469J

Nanostructured organosilicon luminophores as a new concept of nanomaterials for highly efficient down-conversion of light

Ponomarenko S. A., Surin N. M., Borshchev O. V., Skorotetcky M. S., Muzafarov A. M.

InSPIE Nanoscience + Engineering, 2015, 954509-954509; DOI: 10.1117/12.2187281

Rheological properties of nonfunctional derivatives of hyperbranched polycarbosilanes

Sheremetyeva N.A., Myakushev V.D., Muzafarov A.M., Vasiliev V.G., Papkov V.S., Kramarenko E.Y., Pak G.G. 

Russian Chemical Bulletin, 2015, 2145-2151; DOI: 10.1007/s11172-015-1130-0

Aluminum Phthalocyanine on Silica Nanoparticles: Aggregation and Excited States

Lobanov A.V., Sultimova N.B., Levin P.P., Meshkov I.B., Melnikov M.Y.

Macroheterocycles, 2015, 279-283; DOI: 10.6060/mhc150459l

2014

Synthesis of fluorine-containing organosilicon copolymers and their use for the preparation of stable hydrophobic coatings based on the epoxy binder

Soldatov M.A., Sheremetéva N.A., Kalinina A.A., Demchenko N.V., Serenko O.A., Muzafarov A.M.

Russian Chemical Bulletin, 2014, 267-272; DOI: 10.1007/s11172-014-0422-0

Silylated derivatives of azasilacyclopentanes

Salikhov T.R., Kopylov V.M., Shragin D.I.

Russian Journal of General Chemistry, 2014, 875-882; DOI: 10.1134/S1070363214050168

Synthesis and thermal properties of polydimethylsiloxanes modified by decyl and methylundecylenate substituents

Pryakhina T.A., Shragin D.I., Strelkova T.V., Kotov V.M., Buzin M.I., Muzafarov A.M., Demchenko N.V.

Russian Chemical Bulletin, 2014, 1416-1422; DOI: 10.1007/s11172-014-0612-9

Plasmonic Fluorescence Enhancement of DBMBF2 Monomers and DBMBF2–Toluene Exciplexes using Al-Hole Arrays

Schmidt T.M., Bochenkov V.E., Espinoza J.D.A., Smits E.C.P., Muzafarov A.M., Kononevich Yu.N., Sutherland D.S.

Journal of Physical Chemistry C, 2014, 2138-2145; DOI: 10.1021/jp4110823

Synthesis and antioxidant activity of silicon analogue of butylhydroxytoluene

Kononevich Yu.N., Smolski A.S., Demchenko A.M., Muzafarov A.M.

Mendeleev Communications, 2014, 149-151; DOI: 10.1016/j.mencom.2014.04.007

Synthesis of new monofunctional organosilicon molecules – Prospective efficient stoppers for the design of new siloxane polymers of unusual architecture

Anisimov A.A., Kononevich Yu.N., Korlyukov A.A., Arkhipov D.E., Kononova E.G., Peregudov A.S., Shchegolikhina O.I., Muzafarov A.M.

Journal of Organometallic Chemistry, 2014, 79-83; DOI: 10.1016/j.jorganchem.2014.09.001

Nanostructured organosilicon luminophores and their application in highly efficient plastic scintillators

Ponomarenko S.A, Surin N.M., Borshchev O.V., Luponosov Y.N., Akimov D.Y., Alexandrov I.S., Burenkov A.A., Kovalenko A.G., Stekhanov V.N., Kleymyuk E.A., Gritsenko O.T., Cherkaev G.V., Kechek'yan A.S., Serenko O.A., Muzafarov A.M.

Sci. Rep, 2014, 6549; DOI: 10.1038/srep06549

Study of Self-Diffusion of Silicone MQ Resins in Chloroform Solutions by Pulsed Field-Gradient NMR Spectroscopy

Vasil'ev S.G., Volkov V.I., Tatarinova E.A., Muzafarov A.M.

APPLIED MAGNETIC RESONANCE, 2014, 315-328; DOI: 10.1007/s00723-013-0512-4

Thermodynamic properties of carbosilane dendrimers of the third and sixth generations with ethyleneoxide terminal groups

Smirnova N.N., Markin A.V., Letyanina I.A., Sologubov S.S., Novozhilova N.A., Tatarinova E.A., Muzafarov A.M.

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 735-741; DOI: 10.1134/S0036024414050306

2013

Structure and Properties of Composites Based on Polyethylene Oxide and Molecular Silicasol

Serenko O. A., Shevchenko V. G., Zhil’tsov A. S., Chuprakov V. E., Zaderenko T. V., Gritsenko O. T., Mironova M. V., Gorbatsevich O. B., Kazakova V. V., Kulichikhin V. G., Muzafarov A. M.

Nanotechnologies in Russia, 2013, 81–91; DOI: 10.1134/S1995078013010138

New approaches in silicon production and recycling for sustainable future

Muzafarov A. M., Bystrova A. V., Vasilenko N. G. 

Russian Chemical Reviews, 2013, 635-647; DOI: 10.1070/RC2013v082n07ABEH004406

Fracture of polystyrene- and molecular silica sol-based nanocomposites during fast compression

Aleksandrov I. A., Gritsenko O. T., Perov N. S., Getmanova E. V., Obolonkova E. S., Serenko O. A., Shevchenko V. G., Aleksandrov A. I., Muzafarov A. M. 

Technical Physics, 2013, 635-647; DOI: 10.1134/S1063784213010027

Synthesis of diethoxy(phenyl)silane and its polycondensation in acetic acid

Milenin S. A., Kalinina A. A., Demchenko N. V., Vasilenko N.G., Muzafarov A.M.

Russian Chemical Bulletin, 2013, 705-709; DOI: 10.1007/s11172-013-0096-z

Synthesis and properties of carbosilane dendrimers of the third and sixth generations with the ethylene oxide surface layer in bulk and in monolayers at the air-water interface

Novozhilova N. A., Malakhova Yu. N., Buzin M. I., Buzin A. I.,Tatarinova E.A., Vasilenko N.G., Muzafarov A.M. 

Russian Chemical Bulletin, 2013, 2514-2526; DOI: 10.1007/s11172-013-0365-x

Thermodynamic analysis of the glass transition temperatures of the polymer-hybrid nanoparticles systems

Roldugin V.I., Serenko O. A., Getmanova E. V., Karmishina  N.A., Chvalun S.N., Muzafarov A. M.

Doklady Physical Chemistry, 2013, 83 – 87; DOI: 10.1134/S0012501613040088

Carbon-Reinforced Plastics Based on Hybrid Polyimide-Organosilicon Binders

Popova E. N., Yudin V. E, Myagkova L. A., Svetlichnyi V. M., Tatarinova E. A., Muzafarov A. M, Saprykina N. N, Elokhovskii V. Yu, Vaganov G. V.

RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2013, 1873-1879; DOI: 1134/S1070427213120124

Structure of polylactide-modified silicasol nanocomposites based on thermodynamically compatible components

 Zhiltsov A.S., Meshkov I.B., Kurkin T.S., Gorbatsevich O.B., Kazakova V.V., Serenko O.A., Ozerin A.N., Muzafarov A.M., Askadskii A.A. 

Nanotechnologies in Russia, 2013, 644-654; DOI: 10.1134/S1995078013050157

Laser photolysis study of the triplet states of phthalocyanines on the surface of silica nanoparticles in aqueous solutions

Sul'timova N. B., Levin P. P., Lobanov A. V., Muzafarov A. M. 

High Energy Chemistry, 2013, 98-102; DOI: 10.1134/S0018143913030119

Photodegradation of boron difluoride dibenzoylmethanate in solutions

Zakharova G. V., Chibisov A. K., Sazhnikov V. A., Kononevich Yu. N., Muzafarov A. M., Alfimov M. V.

High Energy Chemistry, 2013, 327-330; DOI: 10.1134/S00181 43913060131

A Solid-State NMR Investigation of MQ Silicone Copolymers

Vasil'ev S. G., Volkov V. I., Tatarinova E. A., Muzafarov A. M. 

Applied Magnetic Resonance, 2013, 1015-1025; DOI: 10.1007/s00723-013-0456-8

Synthesis and Photophysical Properties of Alkoxysilyl Derivatives of Dibenzoylmethanatoboron Difluoride

Kononevich Y. N., Meshkov I. B., Voronina N. V., Surin N. M., Sazhnikov V. A., Safonov A. A., Bagaturyants A. A., Alfimov M. V., Muzafarov A. M.

Heteroatom Chemistry, 2013, 271-282; DOI: 10.1002/hc.21091

Synthesis and physical behavior of amphiphilic dendrimers with layered organization of hydrophilic and hydrophobic blocks

Leshchiner I., Boiko N., Kumar J., Richardson R. M, Muzafarov A., Shibaev V.

Colloid Polym Sci, 2013, 927–936; DOI: 10.1007/s00396-012-2811-y

Novel polyolefin/silicon dioxide/H3PO4 composite membranes with spatially heterogeneous structure for phosphoric acid fuel cell

Gruzd A.S., Trofimchuk E.S., Nikonorova N.I., Nesterova E.A., Meshkov I.B., Gallyamov M.O., Khokhlov A.R.

International Journal of Hydrogen Energy, 2013, 4132-4143; DOI: 10.1016/j.ijhydene.2013.01.124

Temperature Dependence of the Hydrodynamic and Conformational Properties of Hyperbranched Polycarbosilanes

Amirova A. I., Sheremetyeva N. A., Filippov A. P.

International Journal of Polymer Analysis and Characterization, 2013, 339-345; DOI: 10.1080/1023666X.2013.784938

Thermodynamics of G-3(D4) and G-6(D4) Carbosilanecyclosiloxane Dendrimers

Smirnova N.N., Markin A.V., Samosudova Ya.S., Ignat’eva G.M., Katarzhnova E.Yu., Muzafarov A.M.

Russian Journal of Physical Chemistry A, 2013, 552–559; DOI: 10.1134/S0036024413040262